The officers will travel to the island in three waves for two weeks each.
Santos and her daughters were volunteering their time Saturday to help the cause.
As of Friday, about 90 percent of Puerto Rico is still without power, while the death toll has climbed to 36 since Hurricane Maria made landfall on September 20.
Santos says it's not an option for her and her girls not to help and many volunteers have similar feelings.
"We do have several teachers here who have extended family in Puerto Rico, and we were all waiting with them to hear that everyone was OK, and it took several days, and I know what that's like to wait, to know whether or not you have a loved one that is OK", said parent Jacqueline Balandra.
London museum crash: terror panic as car hits tourists
In footage shared on social media, police officers could be seen pinning a man on the ground in the aftermath of the incident. The Metropolitan Police said the man had been arrested at the scene and initially received hospital treatment.
Puerto Rico in May filed a form of bankruptcy under the Title III provision in the PROMESA law.
They'll be delivered to Puerto Rico this week.
The governor said he will reiterate to a congressional delegation visiting Puerto Rico today the need for urgent action, due to the magnitude of the challenges.
In addition, two New Jersey National Guard armories continue to accept donations to aid Puerto Rico hurricane relief efforts.
Cruz said, "This is what being a police officer is all about, and this is why we're going down there. The need is unimaginable, and as Central Floridians we need to do all we can to help our brothers and sisters on the island", said Daryl Tol, president and CEO of Florida Hospital and Central Florida Division - Adventist Health System.